钇掺杂二硫化钼/石墨烯的制备及其储锂性能
Preparation and Li-storage performance of yttrium-doped molybdenum disulfide /graphene
朱文广,辛国祥,韩沛,侯渊,张邦文
( 内蒙古科技大学 材料与冶金学院,内蒙古 包头 014010)
摘 要: 采用一步水热法制得钇掺杂二硫化钼/还原氧化石墨烯( Y-MoS2 /rGO) 锂离子电池阳极复合材料,实验结果显示,此复合材料的形貌为三维褶皱 rGO 负载 Y-MoS2 纳米微球,同未掺杂的 MoS2 /rGO电极相比,Y-MoS2 /rGO 电极的可逆容量达到878. 8( 第 2 圈)和823. 7 mAh·g - 1 ( 第 100 圈) ,容量保持率为 93. 7%,Y-MoS2 /rGO 复合材料 储锂性能的提升主要得益于 Y 掺杂 MoS2 和 rGO 的优异导电性及二者的协同作用。
关键词: 石墨烯; 二硫化钼; 掺杂; 锂离子电池
DOI: 10.16559 /j.cnki.2095 - 2295.2022.03.003
基金项目: 内蒙古自治区自然科学基金重大资助项目( 2020ZD17);内蒙古科技大学创新基金资助项目( 0303022003)
作者:朱文广,辛国祥,韩沛,侯渊,张邦文
参考文献:
[1] Bonaccorso F,Colombo L,Yu G.et al.Graphene,related two-dimensional crystals,and hybrid systems for energy conversion and storage [J].Science,2015,347 ( 6217):1246501.
[2] Goriparti S,Miele E,Angelis F D,et al.Review on recent progress of nanostructured anode materials for Li-ion batteries [J].Journal of Power Sources,2014,257: 421.
[3] Man X,Liang P,Shu H.et al.Interface synergistic effect from layered metal sulfides of MoS2 /SnS2 van der waals heterojunction with enhanced Li-Ion storage performance [J].The Journal of Physical Chemistry C, 2018,122( 43):24600.
[4] Feng C,Huang L,Guo Z.et al.Synthesis of tungsten disulfide ( WS2 ) nanoflakes for lithium ion battery application [J].Electrochemistry Communications,2007,9 ( 1):119.
[5]Chen L,Liu Y,Deng Z.et al.Edge-enriched MoS2 @ C/rGO film as self-standing anodes for high-capacity and long-life lithium-ion batteries[J].Science China Materials,2021,64( 1):96.
[6] Zhang R,Tang Z,Wang H.et al.The fabrication of hierarchical MoO2@ MoS2 /rGO composite as high reversible anode material for lithium ion batteries[J].Electrochimica Acta,2020,364( 136996):1.
[7] Yi J,Li M L,Zhou H X.et al.Enhanced tribological properties of Y/MoS2 composite coatings prepared by chemical vapor deposition [J].Ceramics International, 2020,46( 15):23813.11):3272.
[8] Niu Y,Wang P,Zhang M.Tuning the spin polarization in monolayer MoS2 through ( Y,Yb) co-doping[J].New Journal of Chemistry,2020,44( 46):20316.
[9] Hang Y,Yuan X,Lu T.et al.Hydrated vanadium pentoxide /reduced graphene oxide composite cathode material for high-rate lithium ion batteries [J].Journal of Colloid and Interface Science,2021,585: 347.[10] Yu H,Zhang B,Bulin C.et al.High-efficient synthesis of graphene oxide based on improved hummers method [J].Scientific Reports,2016,6( 1):1.
[11] Pan S,Zhang N,Fu Y.Preparation of nanoplatelet-like MoS2 /rGO composite as high-performance anode material for lithium-ion batteries [J].Nano,2019,14 ( 3):1950033.
[12] Ju W,Dong C,Jin B.et al.Composites of reduced graphene oxide and Fe2O3 nanoparticles anchored on MoS2 nanosheets for lithium storage [J].ACS Applied Nano Materials,2020,3( 9):9009.
[13] Qi K,Yuan Z,Hou Y.et al.Facile synthesis and improved Li-storage performance of Fe-doped MoS2 /reduced graphene oxide as anode materials [J].Applied Surface Science,2019,483: 688.
[14] Xiao J,Wang X,Yang X.et al.Electrochemically induced high capacity displacement reaction of PEO/ MoS2 /Graphene nanocomposites with lithium [J].Advanced Functional Materials,2011,21( 15):2840.
[15] Hou J,Qin J,Zhang X.et al.2D space-confined synthesis of few-layer MoS2 anchored on carbon nanosheet for lithium-ion battery anode [J].ACS Nano,2015,9 ( 4):3837.