06 以席夫碱构筑的配位簇合物的合成及结构

王丽;王延铭;金振军;李国祥;

• 1:内蒙古科技大学化学与化工学院内蒙古自治区煤化工与煤炭综合利用重点实验室

• 2:内蒙古自治区稀土产品质量监督检验研究院业务管理科

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摘要(Abstract)：                

利用溶剂热下的邻香草醛与四乙烯五胺的原位缩合反应,再进一步与稀土离子配位得到了一个新的配合物,通过红外光谱、X-射线单晶衍射等测试方法对其结构进行了分析,结果表明:配合物的分子式为[Tm(L)(NCS)],属于单斜晶系,空间群是P2(1)/n.配合物中存在分子间氢键和分子内氢键,使晶体结构更加稳定.

关键词(KeyWords)：                    席夫碱;配位簇合物;单晶结构

基金项目(Foundation):                    内蒙古自治区科技大学创新基金资助项目(2016QDL-S04)

作者(Author):                    王丽;王延铭;金振军;李国祥;

Email:                                    

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