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09.化学浸泡法研究稀土镧对铝合金的缓蚀性能

日期:2015-05-27 10:41:45 点击:

                                                                     杨文煜刘金彦*周星赵晓

(内蒙古科技大学化学与化工学院,包头,014010

摘要:本文采用化学浸泡法,研究了在1.0mol/L的氯化钠溶液中,LaCl3作为缓蚀剂时,缓蚀剂的浓度、温度以及浸泡时间对2024铝合金的缓蚀效率的影响。研究表明,La3+作缓蚀剂时,其在浓度为1.0mmol/L、温度为30℃和浸泡时间是48h时缓蚀效率达到最高。并且温度的升高和浸泡时间的延长都有利于缓蚀剂抑制铝合金的腐蚀。本文还利用阿伦尼乌斯方程来计算腐蚀活化能,并利用其来分析浓度、温度以及浸泡时间对腐蚀速率的影响。

关键词:镧,铝合金,缓蚀作用,化学浸泡

中图分类号:TG172文献标识码:A

The study of inhibition properties of rare earth lanthanumon aluminum alloy by chemical soaking method

Yang Wen-yu  LiuJin-yan  Zhou xing  Zhao xiao

Chemistry and Chemical Engineering School , InnerMongolia University of Science & Technology, Baotou 014010, China

AbstractThe effects of inhibitorconcentration, temperature and immersion time on the corrosion rate of 2024aluminium alloy in 1.0mol/L NaCl solution werestudied by chemical soaking method while using LaCl3 as inhibitor.The results reveal that the corrosion inhibitor ishighly efficient when La3+ concentration is 1.0mmol/L, and the immersiontime is 48 h at temperature of 30. High temperature and soaking time extension are infavour of the corrosion inhibition on the aluminum alloy. The corrosionactivation energy was calculated and the effects of concentration, temperatureand soaking time were analyzed using Arrhenius equation.

Key wordsLanthanum, Aluminium alloy,Inhibition effect, Chemical soaking



*第一作者:杨文煜,(1994-)女,湖北黄冈人,内蒙科技大学本科生. 通讯联系人:刘金彦,教授,博士,研究方向:金属腐蚀与防护.资助项目:国家自然科学基金(21463016

地址:内蒙古包头市昆都仑区阿尔丁大街7号 邮编:014010 电话:0472-5951610或0472-5953910 Email:cky@imust.edu.cn nkdxb@imust.edu.cn

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